SnAP TM Reagent

ALDRICH/798886

CAS Number: 1452829-00-3
Empirical Formula (Hill Notation): C₁₅H₃₅NSSn
Molecular Weight: 380.22
MDL Number: MFCD23703162
Linear Formula: C₁₅H₃₅NSSn
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-798886-1G	1 g	$173.00 1/EA		Add To Favorites

SnAP Ring Orientation

Properties
Descriptions
Safety Info.
Basic Data

density	1.158 at 25 °C
form	liquid
InChI	1S/3C4H9.C3H8NS.Sn/c31-3-4-2;1-5-3-2-4;/h31,3-4H2,2H3;1-4H2;
InChI key	DYBMHPJDHUKXRF-UHFFFAOYSA-N
Quality Level	100
refractive index	n/D 1.512
SMILES string	CCCC[Sn](CCCC)(CSCCN)CCCC
storage temp.	−20°C

Application:	SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group
Application:	SnAP TM Reagent may be used to synthesize 3-substituted thiomorpholines from aldehydes. It may also be used in the preparation of unprotected, saturated N-heterocyclic compounds. Automate your N-heterocycle formation with Synple Automated Synthesis Platform (SYNPLE-SC002 )
General description:	SnAP (Sn amino protocol) reagents have been developed by the Bode group. SnAP reagents are air and moisture stable. They can be prepared from simple reactions with cheap raw materials. SnAP 2-Spiro-(4-Pip) M, also referred to as SnAP 2-spiro-(4-piperdine) morpholine, is a regioisomeric SnAP reagent. This reagent can be prepared from N-Boc piperidone.
Other Notes:	Technology spotlight: SnAP Reagents Professor product portal: Jeffrey Bode Research Group SnAP Reagents for the Synthesis of Piperazines and Morpholines SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles
Packaging:	1 g in glass bottle

Symbol	GHS06,GHS09
Signal word	Danger
Hazard statements	H301 + H311 + H331 - H315 - H319 - H335 - H410
Precautionary statements	P273 - P280 - P301 + P310 + P330 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338
RIDADR	UN 2788 6.1 / PGIII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Density	1.158 at 25 °C
Refractive Index	n/D 1.512
Storage Temp.	−20°C
UNSPSC	12352103

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