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(dppf)Ni(o-tolyl)Cl

ALDRICH/802948

Synonym: Buchwald Ni Catalyst

CAS Number: 1501945-23-8
Empirical Formula (Hill Notation): C41H35ClFeNiP2
Molecular Weight: 739.66
MDL Number: MFCD28411349
Linear Formula: C41H35ClFeNiP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-802948-250MG 250 mg
 $134.00
1/EA		 Add To Favorites
45-802948-1G 1 g
 $405.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 802948-1G

 

assay 95%
form powder
InChI 1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1
InChI key LGLPATFHWYLMCO-UHFFFAOYSA-M
mp 173 °C
reaction suitability core: nickel
  reaction type: Cross Couplings
  reagent type: catalyst
SMILES string CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]
storage temp. 2-8°C
General description: (dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
RIDADR UN 3077 9 / PGIII
Purity 95%
mp 173 °C
Storage Temp. 2-8°C
UNSPSC 12161600

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