[Ir{dFCF₃ppy}₂(bpy)]PF₆

ALDRICH/804215

Synonym: [Ir[dF(CF3)2ppy]2(bpy)]PF6

CAS Number: 1092775-62-6
Empirical Formula (Hill Notation): C₃₄H₁₈F₁₆IrN₄P
Molecular Weight: 1009.70
MDL Number: MFCD28987331
Linear Formula: C₃₄H₁₈F₁₆IrN₄P
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-804215-50MG	50 mg	$105.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	powder
InChI	1S/2C12H5F5N.C10H8N2.F5P.FH.Ir/c213-8-2-3-9(10(14)5-8)11-4-1-7(6-18-11)12(15,16)17;1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-6(2,3,4)5;;/h21-2,4-6H;1-8H;;1H;/q;;;;;+1/p-1
InChI key	DZIQZTFRUCLPRL-UHFFFAOYSA-M
photocatalyst activation	450 nm
Quality Level	100
reaction suitability	core: iridium
	reagent type: catalyst reaction type: Photocatalysis
SMILES string	FP(F)(F)(F)F.FC1=CC(F)=C(C2=[N]3C=C(C(F)(F)F)C=C2)C([Ir+]345([N]6=C(C7=CC=CC=[N]75)C=CC=C6)[N]8=C(C9=C(F)C=C(F)C=C94)C=CC(C(F)(F)F)=C8)=C1.[F-]

Application:	When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp³ hybridized trifluoroborates with aryl bromides under exceptionally mild conditions. Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 )
Packaging:	50 mg in glass bottle

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

UNSPSC

12161600

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