2,2′-Bipyrazine
ALDRICH/804533
Synonym: 2,2′-Bipyrazinyl; 2,2′-Dipyrazinyl
CAS Number: 10199-00-5
Empirical Formula (Hill Notation): C8H6N4
Molecular Weight: 158.16
Linear Formula: C8H6N4
Product Type: Chemical
assay | 97% |
form | powder |
InChI | 1S/C8H6N4/c1-3-11-7(5-9-1 |
InChI key | DFXNVSIALRDJHY-UHFFFAOYSA |
mp | 185-188 °C |
Quality Level | 100 |
reaction suitability | core: palladium |
reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst |
Application: | 2,2′-Bipyrazine (bpz) can be used as a ligand to synthesize strongly oxidizing photocatalysts. Ruthenium-based homoleptic tris(bipyrazyl) complex [(Ru(bpz)32+] derived from 2,2′-bipyrazine ligand can be used as an effective photocatalyst for oxidatively induced organic transformations. For instance, [(Ru(bpz)32+] is capable of promoting radical cation mediated Diels–Alder cycloadditions, radical thiol-ene couplings, photooxygenation reactions, and [3+2] cycloaddition reactions. |
Packaging: | 1 g in glass bottle |
Packaging: | 250 mg in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 97% |
mp | 185-188 °C |
UNSPSC | 12161600 |