(R,S)-Bode Kinetic Resolution Catalyst

ALDRICH/804568

Synonym: (4aR,9aS)-6-Bromo-4-hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one

CAS Number: 1394957-71-1
Empirical Formula (Hill Notation): C₁₁H₁₀BrNO₃
Molecular Weight: 284.11
Linear Formula: C₁₁H₁₀BrNO₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-804568-100MG	100 mg	$152.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

form	solution
InChI	1S/C11H10BrNO3/c12-7-2-1-6-3-9-11(8(6)4-7)13(15)10(14)5-16-9/h1-2,4,9,11,15H,3,5H2/t9-,11+/m0/s1
InChI key	FQXSUQCCAHKURK-GXSJLCMTSA-N
Quality Level	100
SMILES string	O=C(CO1)N(O)[C@@]2([H])[C@]1([H])CC3=CC=C(Br)C=C32
storage temp.	15-25°C

Application:	The following hydroxamic acid catalyst was shown by Bode and coworkers to assist in the kinetic resolution of cyclic amines through acylation of one enantiomer, which can be controlled using either the (R or S)- or (S or R)-Bode Kinetic Resolution Catalyst, both of which are also available through Sigma-Aldrich. It can also be employed in the preparation of nonracemic piperidines by kinetic resolution using an α-hydroxy-α′, β-unsaturated ketone in the presence of a pyrrolotriazolium salt.
Other Notes:	Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution of N-heterocycles
Packaging:	100 mg in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302
Precautionary statements	P301 + P312 + P330
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Storage Temp.	15-25°C
UNSPSC	12352101

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