DavePhos-Pd-G3

ALDRICH/804959 - 95%

Synonym: Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)

CAS Number: 1445085-87-9
Empirical Formula (Hill Notation): C₃₉H₄₉N₂O₃PPdS
Molecular Weight: 763.28
MDL Number: MFCD27978422
Linear Formula: C₃₉H₄₉N₂O₃PPdS
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-804959-250MG	250 mg	$144.00 1/EA	Add To Favorites
45-804959-1G	1 g	$393.00 1/EA	Add To Favorites
45-804959-5G	5 g	$1580.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 804959-1G

Properties
Descriptions
Safety Info.
Basic Data

assay	95%
feature	generation 3
form	solid
functional group	phosphine
impurities	<5% THF
InChI	1S/C26H36NP.C12H10N.CH4O3S.Pd/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h9-12,17-22H,3-8,13-16H2,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key	FBIRGVXUSGLNQE-UHFFFAOYSA-M
mp	183-200 °C (decomp)
Quality Level	100
reaction suitability	core: palladium
	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
SMILES string	CN(C)C1=C(C2=C(P(C3CCCCC3)C4CCCCC4)C=CC=C2)C=CC=C1.NC5=C(C6=C([Pd]OS(C)(=O)=O)C=CC=C6)C=CC=C5

Application:	Pd precatalyst for cross-coupling
General description:	DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
Packaging:	1, 5 g in glass bottle
Packaging:	250 mg in glass bottle

Symbol	GHS08
Signal word	Warning
Hazard statements	H351
Precautionary statements	P201 - P202 - P280 - P308 + P313 - P405 - P501
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable
Supplemental Hazard Statements	EUH019

Purity	95%
mp	183-200 °C (decomp)
UNSPSC	12161600

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