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FK 102 Co(III) TFSI salt

ALDRICH/805203

Synonym: tris(2-(1H-pyrazol-1-yl)pyridine)cobalt(III) tri[bis(trifluoromethane)sulfonimide

Empirical Formula (Hill Notation): C30H21CoN12O12S6F18
Molecular Weight: 1334.86
Linear Formula: C30H21CoN12O12S6F18
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-805203-5G 5 g
$89.00
1/EA
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This image depicts SKU: 805203-5G

 

assay 98%
form powder
InChI 1S/3C8H7N3.3C2F6NO4S2.Co/c3*1-2-5-9-8(4-1)11-7-3-6-10-11;3*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h3*1-7H;;;;/q;;;3*-1;+3
InChI key ILXRZLQXWLMDFQ-UHFFFAOYSA-N
mp 194-199 °C
Quality Level 100 
SMILES string O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.N1(C2=NC=CC=C2)N=CC=C1.C3(N4C=CC=N4)=CC=CC=N3.C5(N6C=CC=N6)=CC=CC=N5.[Co+3]
Application: FK 102 Co(III) TFSI salt can be majorly used in the fabrication of dye sensitized solar cells (DSSCs) and perovskite based solar cells (PSCs).
Application: Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices. FK102 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and particularly at lower light levels(e.g. for indoor applications), significantly increase device power output.
Recommended use:
In liquid-based electrolytes: typically 0.15-0.2 M of Co(II) and ca. 0.05 M Co(II)
In solid-state photovoltaic cells: up to 10 weight % added to the hole transport material system.
General description: FK 102 Co(III) TFSI salt is a cobalt(III) complex that can be used as a p-type dopant to control the type and density of charge carriers in both organic and inorganic semiconductors. The solubility of TFSI allows an increase in the doping potential for hole-conductors in electrochemical devices.
Legal Information: Product of Greatcell Solar Materials Pty Ltd. Greatcell Solar is a registered trademark of Greatcell Solar Materials Pty Ltd.
Packaging: 5 g in poly bottle
Purity 98%
mp 194-199 °C
UNSPSC 12352103

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