(S,R,R)-Elenor Amination Reagent

ALDRICH/808024

Synonym: 3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-

CAS Number: 139331-02-5
Empirical Formula (Hill Notation): C₁₁H₁₈N₂O₄S
Molecular Weight: 274.34
Linear Formula: C₁₁H₁₈N₂O₄S
Product Type: Chemical

form	powder
InChI	1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m1/s1
InChI key	FYSORZDAOUCPGD-SOCHQFKDSA-N
Quality Level	100
SMILES string	O=C(N1S(C[C@]2(C3(C)C)CC[C@]3([H])C[C@@]12[H])(=O)=O)NO
storage temp.	2-8°C

Application:	The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air.
Other Notes:	Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction
Packaging:	1 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H315 - H319 - H335
Precautionary statements	P302 + P352 - P305 + P351 + P338
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Storage Temp.	2-8°C
UNSPSC	12352000