Fe/ppm Pd for nitro group reductions
ALDRICH/809330
MDL Number: MFCD00011005
Product Type: Chemical
| composition | FeCl2 (372870), 23.3-27.4 wt. % |
| MgCl2 (M8266), 15.3-18.8 wt. % | |
| Pd (203939), <0.3 wt. % | |
| THF (186562), 53.5-61.6 wt. % | |
| form | solid |
| Quality Level | 100  |
| reaction suitability | core: iron |
| reagent type: catalyst | |
| storage temp. | 2-8°C |
| Application: | When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M , a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups. |
| Caution: | Handle under nitrogen and store under argon in refrigerator. |
| Other Notes: | Safe and Selective Nitro Group Reductions Catalyzed by Sustainable and Recyclable Fe/ppm Pd Nanoparticles in Water at Room Temperature  |
| Other Notes: | Watch Professor Lipshutz talk about Fe/ppm Pd in this webinar: From milligrams to kilograms: synthetic chemistry following nature′s lead |
| Packaging: | 500 mg in glass bottle |
| Symbol |     GHS02,GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225 - H290 - H302 - H318 - H335 - H351 |
| Precautionary statements | P201 - P210 - P233 - P261 - P280 - P305 + P351 + P338 + P310 |
| RIDADR | UN 1773 8 / PGIII |
| WGK Germany | WGK 2 |
| Flash Point(F) | 1.4 °F |
| Flash Point(C) | -17 °C |
| Supplemental Hazard Statements | EUH018 - EUH019 |
| Storage Temp. | 2-8°C |
| UNSPSC | 12161600 |