(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

ALDRICH/88719 - ≥97%

Synonym: (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS); Josiphos SL-J002-1

CAS Number: 155830-69-6
Empirical Formula (Hill Notation): C₃₂H₄₀FeP₂
Molecular Weight: 542.45
MDL Number: MFCD01074442
Linear Formula: C₃₂H₄₀FeP₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-88719-100MG	100 mg	$124.00 1/EA	Add To Favorites
45-88719-500MG	500 mg	$587.00 1/EA	Add To Favorites
45-88719-1G	1 g	$682.00 1/EA	Add To Favorites
45-88719-5G	5 g	$2870.00 1/EA	Add To Favorites
45-88719-50G	50 g	$10770.00 1/EA	Add To Favorites
45-88719-100G	100 g	$18080.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥97%
form	crystals
InChI	1S/C27H35P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-21H,1-7H3;1-5H;/t21-;;/m1../s1
InChI key	STAGMXYQPGLLTD-GHVWMZMZSA-N
optical purity	ee: ≥99%
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C(C)(C)C)C(C)(C)C

Application:	It may be used as a ligand in the palladium-catalyzed alkoxycarbonylation of 6-bromo-1,4-benzodioxane with sodium tert-butoxide to form the corresponding tert-butyl ester.
General description:	(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (PPF-^tBu) is a chiral ferrocenyl diphosphine ligand.
General description:	sold in collaboration with Solvias AG
Packaging:	1, 5 g in glass bottle
Packaging:	100, 500 mg in glass bottle
Packaging:	Bottomless glass bottle. Contents are inside inserted fused cone.

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97%
UNSPSC	12352005

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