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(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

ALDRICH/88733 - ≥97%

Synonym: (2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(dicyclohexylphosphino)ferrocene (acc to CAS); Josiphos SL-J009-1

CAS Number: 158923-11-6
Empirical Formula (Hill Notation): C32H52FeP2
Molecular Weight: 554.55
MDL Number: MFCD08543435
Linear Formula: C32H52FeP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-88733-100MG 100 mg
 $126.00
1/EA		 Add To Favorites
45-88733-500MG 500 mg
 $360.00
1/EA		 Add To Favorites
45-88733-1G 1 g
 $682.00
1/EA		 Add To Favorites
45-88733-5G 5 g
 $2500.00
1/EA		 Add To Favorites

 

assay ≥97%
form powder
functional group phosphine
InChI 1S/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m1../s1
InChI key FFFWTQLOUUWUJJ-GHVWMZMZSA-N
optical purity ee: ≥99%
reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: ligand
reaction type: Cross Couplings
SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C3CCCCC3)C4CCCCC4)P(C(C)(C)C)C(C)(C)C
Application: It may be used as a ligand in the palladium catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates.
General description: (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine (CyPF-tBu) is a chiral ferrocenyl diphosphine ligand.
General description: sold in collaboration with Solvias AG
Packaging: 1, 5 g in glass bottle
Packaging: 100, 500 mg in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97%
UNSPSC 12352000

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