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(R)-1-[(SP)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine

ALDRICH/88755 - 97%

Synonym: (1R)-1-[Bis(1,1-dimethylethyl)phosphino]-2-[(1R)-1-[bis(2-methylphenyl)phosphino]ethyl]ferrocene (acc to CAS); Josiphos SL-J505-1

CAS Number: 849924-76-1
Empirical Formula (Hill Notation): C34H44FeP2
Molecular Weight: 570.51
MDL Number: MFCD08561172
Linear Formula: C34H44FeP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-88755-100MG 100 mg
 $0.00
1/EA
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45-88755-500MG 500 mg
 $0.00
1/EA
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45-88755-1G 1 g
 $821.00
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45-88755-50G 50 g
 $24590.00
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45-88755-100G 100 g
 $34470.00
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assay 97%
form powder
functional group phosphine
InChI 1S/C29H39P2.C5H5.Fe/c1-21-15-10-12-18-25(21)30(26-19-13-11-16-22(26)2)23(3)24-17-14-20-27(24)31(28(4,5)6)29(7,8)9;1-2-4-5-3-1;/h10-20,23H,1-9H3;1-5H;/t23-;;/m1../s1
InChI key DSZYQALCGVODLB-MQWQBNKOSA-N
optical purity ee: ≥99%
Quality Level 100 
SMILES string [Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(C(C)(C)C)C(C)(C)C)P(c3ccccc3C)c4ccccc4C
Application: It may be used as ligand to prepare 4,7-amino-1,10-phenanthroline containing N- and O- containing macrocyclic ligands via palladium catalyzed amination reactions.
General description: (R)-1-[(SP)-2-(Di-tert-butylphosphino)ferrocenyl]ethylbis(2-methylphenyl)phosphine is a chiral ferrocenyl diphosphine ligand.
General description: sold in collaboration with Solvias AG
Packaging: 1, 5 g in glass bottle
Packaging: 100, 500 mg in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 97%
UNSPSC 12352005

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