Isopropoxy(phenyl)silane
ALDRICH/900258
Synonym: RubenSilane
CAS Number: 910037-63-7
Empirical Formula (Hill Notation): C9H14OSi
Molecular Weight: 166.29
Linear Formula: C9H14OSi
Product Type: Chemical
| density | 0.926 g/mL |
| form | liquid |
| Quality Level | 100  |
| reaction suitability | reagent type: reductant reaction type: Reductions |
| refractive index | n |
| storage temp. | 2-8°C |
| Application: | Isopropoxy(phenyl)silane can be used as a hydride source for alkene hydrofunctionalization reactions in the presence of metal catalysts, particularly under aprotic, nonalcoholic conditions. This reagent is considered as one of the most efficient stoichiometric reductants than phenylsilane because of its ability to exclude alcohol solvent from a series of catalytic reactions. When utilized, it allows the researcher to significantly decrease catalyst loadings, lower reaction temperatures, and employ more diverse solvents in iron- and manganese-catalyzed Mukaiyama hydrofunctionalizations. It can be used as a reagent in: • The hydrogenation of olefins • Branch-selective olefin cross-coupling reactions • Markovnikov alkene hydration/amination reactions |
| General description: | Isopropoxy(phenyl)silane is used as a stoichiometric reductant that allows for a significant decrease in catalyst loading, lower reaction temperatures, a wide range of functional group tolerance, and more diverse solvents in metal-catalyzed Mukaiyama hydrofunctionalizations. |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Density | 0.926 g/mL |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352005 |