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Isopropoxy(phenyl)silane

ALDRICH/900258

Synonym: RubenSilane

CAS Number: 910037-63-7
Empirical Formula (Hill Notation): C9H14OSi
Molecular Weight: 166.29
MDL Number: MFCD31707672
Linear Formula: C9H14OSi
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-900258-1G 1 g
 $161.00
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45-900258-5G 5 g
 $0.00
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density 0.926 g/mL
form liquid
InChI 1S/C9H14OSi/c1-8(2)10-11-9-6-4-3-5-7-9/h3-8H,11H2,1-2H3
InChI key XYMAHMLQCLMTDN-UHFFFAOYSA-N
Quality Level 100 
reaction suitability reagent type: reductant
reaction type: Reductions
refractive index n/D 1.4799
SMILES string [SiH2](OC(C)C)c1ccccc1
storage temp. 2-8°C
Application: Isopropoxy(phenyl)silane can be used as a hydride source for alkene hydrofunctionalization reactions in the presence of metal catalysts, particularly under aprotic, nonalcoholic conditions. This reagent is considered as one of the most efficient stoichiometric reductants than phenylsilane because of its ability to exclude alcohol solvent from a series of catalytic reactions. When utilized, it allows the researcher to significantly decrease catalyst loadings, lower reaction temperatures, and employ more diverse solvents in iron- and manganese-catalyzed Mukaiyama hydrofunctionalizations.
It can be used as a reagent in:
• The hydrogenation of olefins
• Branch-selective olefin cross-coupling reactions
• Markovnikov alkene hydration/amination reactions
General description: Isopropoxy(phenyl)silane is used as a stoichiometric reductant that allows for a significant decrease in catalyst loading, lower reaction temperatures, a wide range of functional group tolerance, and more diverse solvents in metal-catalyzed Mukaiyama hydrofunctionalizations.
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Density 0.926 g/mL
Refractive Index n/D 1.4799
Storage Temp. 2-8°C
UNSPSC 12352005

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