Bis(3,5-bis(trifluoromethyl)phenyl)(2′,6′-bis(dimethylamino)-3,6-dimethoxybiphenyl-2-yl)phosphine

ALDRICH/900277 - ≥95%

Synonym: 2′-(Bis(3,5-bis(trifluoromethyl)phenyl)phosphanyl)-3′,6′-dimethoxy-N ,N ,N ,N -tetramethyl-[1,1′-biphenyl]-2,6-diamine; 2′-(Bis(3,5-bis(trifluoromethyl)phenyl)phosphanyl)-3′,6′-dimethoxyN₂,N₂,N₆,N₆ -tetramethyl-[1,1′-biphenyl]-2,6-diamine; 2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-3,6-dimethoxy -2′,6′-bis(dimethylamino)-1,1′-biphenyl

CAS Number: 1810068-30-4
Empirical Formula (Hill Notation): C₃₄H₂₉F₁₂N₂O₂P
Molecular Weight: 756.56
MDL Number: MFCD29905024
Linear Formula: C₃₄H₂₉F₁₂N₂O₂P
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-900277-250MG	250 mg	$626.00 1/EA	Add To Favorites
45-900277-1G	1 g	$2400.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	≥95%
form	powder or crystals
functional group	phosphine
InChI	1S/C34H29F12N2O2P/c1-47(2)24-8-7-9-25(48(3)4)28(24)29-26(49-5)10-11-27(50-6)30(29)51(22-14-18(31(35,36)37)12-19(15-22)32(38,39)40)23-16-20(33(41,42)43)13-21(17-23)34(44,45)46/h7-17H,1-6H3
InChI key	RXBSKAKCDMMHNB-UHFFFAOYSA-N
mp	160.3 °C
Quality Level	100
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
	reagent type: catalyst reaction type: Cross Couplings
	reagent type: ligand
SMILES string	FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(c3c(ccc(c3c4c(cccc4N(C)C)N(C)C)OC)OC)c2cc(cc(c2)C(F)(F)F)C(F)(F)F

Application:

As the Pd G4 complex, this revolutionary ligand from the Buchwald group offers best-in-class performance in the arylation of sterically hindered secondary amines.

Hazard statements	H413
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥95%
mp	160.3 °C
UNSPSC	12352128

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