Di-t-butyl oxaziridine
ALDRICH/900624 - ≥95%
Synonym: Kurti oxaziridine
CAS Number: 56741-77-6
Empirical Formula (Hill Notation): C9H19NO
Molecular Weight: 157.25
Linear Formula: C9H19NO
Product Type: Chemical
assay | ≥95% |
availability | available only in USA |
density | 0.90 g/mL |
form | liquid |
Quality Level | 100 |
refractive index | n |
SMILES string | CC(C)(C)C1(NO1)C(C)(C)C |
storage temp. | 2-8°C |
Application: | This oxaziridine has been used in synthetic methods for amination, heteroatom transfer, and C-H functionalization. Recently, the lab of Laszlo Kurti demonstrated its application for direct electrophilic primary and secondary amination of arylmetals in the presence of Cu(I) salts -- void of precious metal catalysts, ligands, protecting groups, or directing groups. |
Other Notes: | Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals Rapid heteroatom transfer to arylmetals utilizing multifunctional reagent scaffolds Diverse sp3 C-H functionalization through alcohol β-sulfonyloxylation |
Symbol | GHS02 |
Signal word | Danger |
Hazard statements | H242 |
Precautionary statements | P210 - P234 - P235 - P240 - P370 + P378 - P403 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | 143.6 °F |
Flash Point(C) | 62 °C |
Purity | ≥95% |
Density | 0.90 g/mL |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352000 |