2,4,6-Tri(p-tolyl)pyrylium tetrafluoroborate salt
ALDRICH/900685 - ≥95%
CAS Number: 2713-21-5
Empirical Formula (Hill Notation): C26H23BF4O
Molecular Weight: 438.26
Linear Formula: C26H23BF4O
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 900685-250MG.
| assay | ≥95% |
| form | powder |
| mp | 298-303 °C |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst reaction type: Photocatalysis |
| Application: | Excitable by blue LEDs, this photocatalyst was reported by the Nicewicz laboratory for catalysis of O-aryl carbamothioates to S-aryl carbamothioates at ambient temperatures, an improvement from the elevated reaction temperatures traditionally needed in the Newman-Kwart rearrangment or palladium catalysis. Effective for scale-up or flow chemistry, this triarylpyrylium salt provides convenient access to thiophenols from phenols. |
| Application: | It can also catalyze visible light-initiated, living cationic polymerization of 4-methoxystyrene with methanol under metal-free conditions. Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 ) |
| Other Notes: | Ambient-Temperature Newman-Kwart Rearrangement Mediated by Organic Photoredox Catalysis  Cycloaddition Reactions Initiated by Photochemically Excited Pyrylium Salts |
| Packaging: | 250 mg in glass insert |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥95% |
| mp | 298-303 °C |
| UNSPSC | 12161600 |