Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)

ALDRICH/900943

Synonym: SK-J003-1n

CAS Number: 2049086-35-1
Empirical Formula (Hill Notation): C₄₃H₆₀ClFeNNiP₂
Molecular Weight: 802.88
Linear Formula: C₄₃H₆₀ClFeNNiP₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-900943-250MG	250 mg	$268.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

form	powder or solid
Quality Level	100
reaction suitability	core: nickel
	reaction type: Cross Couplings
	reagent type: catalyst reaction type: Asymmetric synthesis
SMILES string	Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]

Application:	Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.
Other Notes:	Nickel-Catalyzed Monoarylation of Ammonia Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

Symbol	GHS07,GHS08,GHS09
Signal word	Warning
Hazard statements	H315 - H361d - H411
Precautionary statements	P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
RIDADR	UN 3175 4.1 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

UNSPSC

12352103

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