Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)

ALDRICH/900944 - ≥95%

Synonym: SK-J002-1n

CAS Number: 2049086-34-0
Empirical Formula (Hill Notation): C₃₉H₄₄ClFeNNiP₂
Molecular Weight: 738.71
Linear Formula: C₃₉H₄₄ClFeNNiP₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-900944-250MG	250 mg	$268.00 1/EA	Add To Favorites

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Properties
Descriptions
Safety Info.
Basic Data

assay	≥95%
form	powder or solid
Quality Level	100
reaction suitability	core: nickel
	reaction type: Cross Couplings
	reagent type: catalyst reaction type: Asymmetric synthesis
SMILES string	CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=CC=C2)C3=CC=CC=C3.[Ni+2]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]

Application:	Amination of aryl chlorides with ammonia.
Other Notes:	Nickel-Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

Symbol	GHS07,GHS08,GHS09
Signal word	Warning
Hazard statements	H315 - H361d - H411
Precautionary statements	P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
RIDADR	UN 3175 4.1 / PGII
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥95%
UNSPSC	12352103

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