Phenox O-PC™ A0202
ALDRICH/901111 - New Iridium, ≥97%
Synonym: 3,7-Di([1,1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine; Miyake organophotoredox catalyst; 3,7-Di(4-biphenyl) 1-
CAS Number: 1987900-95-7
Empirical Formula (Hill Notation): C46H31NO
Molecular Weight: 613.74
Linear Formula: C46H31NO
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 901111-100MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 901111-1G.
| assay | ≥97% |
| form | powder or crystals |
| mp | 171 °C |
| photocatalyst activation | 400 nm |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst reaction type: Photocatalysis |
| SMILES string | C1(C=CC(C2=CC=C(C3=CC=CC= |
| Application: | This phenoxazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901112 ) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake Research Group. Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 ) |
| Legal Information: | Patent application PCT/US2016/058245. Sold in collaboration with New Iridium Inc. For orders greater than 25g, please contact New Iridium at chern@newiridium.com or visit https://www.newiridium.co |
| Legal Information: | Phenox O-PC is a trademark of New Iridium LLC |
| Other Notes: | Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals  Organocatalyzed Atom Transfer Radical Polymerization Driven by Visible Light Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥97% |
| mp | 171 °C |
| UNSPSC | 12161600 |