Phenox O-PC^™ A0202

ALDRICH/901111 - New Iridium, ≥97%

Synonym: 3,7-Di([1,1′-biphenyl]-4-yl)-10-(naphthalen-1-yl)-10H-phenoxazine; Miyake organophotoredox catalyst; 3,7-Di(4-biphenyl) 1-naphthalene-10-phenoxazine; PhenO_1Naph_Biph

CAS Number: 1987900-95-7
Empirical Formula (Hill Notation): C₄₆H₃₁NO
Molecular Weight: 613.74
MDL Number: MFCD31619181
Linear Formula: C₄₆H₃₁NO
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-901111-100MG	100 mg	$189.00 1/EA	Add To Favorites
45-901111-1G	1 g	$1240.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 901111-100MG.

Properties
Descriptions
Safety Info.
Basic Data

assay	≥97%
form	powder or crystals
InChI	1S/C46H31NO/c1-3-10-32(11-4-1)34-18-22-36(23-19-34)39-26-28-43-45(30-39)48-46-31-40(37-24-20-35(21-25-37)33-12-5-2-6-13-33)27-29-44(46)47(43)42-17-9-15-38-14-7-8-16-41(38)42/h1-31H
InChI key	IGGSSEOAGCUGDJ-UHFFFAOYSA-N
mp	171 °C
photocatalyst activation	400 nm
Quality Level	100
reaction suitability	reagent type: catalyst reaction type: Photocatalysis
SMILES string	C1(C=CC(C2=CC=C(C3=CC=CC=C3)C=C2)=C4)=C4OC(C=C(C5=CC=C(C6=CC=CC=C6)C=C5)C=C7)=C7N1C8=C(C=CC=C9)C9=CC=C8

Application:	This phenoxazine-based organic photoredox catalyst (in addition to the dihydrophenazine catalyst 901112 ) was designed to be a strong excited-state reductant and possesses advanced photophysical and electrochemical properties, enabling it to serve as a sustainable replacement for ruthenium- or iridium-based photoredox catalysts. For example, dihydrophenazine and phenoxazine derivatives were demonstrated to replace ruthenium or iridium complexes in the application of photoredox-catalyzed atom transfer radical polymerization (ATRP) for controlled polymer synthesis and small molecule transformations such as trifluoromethylation, atom transfer radical addition, and dual Nickel/photoredox catalyzed C-N and C-S cross-couplings. Dihydrophenazine- and phenoxazine-based organic photoredox catalysts were introduced in collaboration with the Miyake Research Group. Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 )
Legal Information:	Patent application PCT/US2016/058245. Sold in collaboration with New Iridium Inc. For orders greater than 25g, please contact New Iridium at chern@newiridium.com or visit https://www.newiridium.com.
Legal Information:	Phenox O-PC is a trademark of New Iridium LLC
Other Notes:	Strongly Reducing Visible Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals Organocatalyzed Atom Transfer Radical Polymerization Driven by Visible Light Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization

RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	≥97%
mp	171 °C
UNSPSC	12161600

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