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cis-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl](2-methylphenyl)nickel(II) chloride

ALDRICH/901166

Synonym: cis-((S)-BINAP)Ni(o-tolyl)Cl

CAS Number: 1594113-05-9
Empirical Formula (Hill Notation): C51H39ClNiP2
Molecular Weight: 807.95
Linear Formula: C51H39ClNiP2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-901166-100MG 100 mg
 $170.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 901166-100MG.

 

form powder or solid
mp >300 °C
Quality Level 100 
reaction suitability core: nickel
  reaction type: Cross Couplings
  reagent type: catalyst
SMILES string Cl[Ni]1(P(C2=C([H])C([H])=C([H])C([H])=C2[H])(C3=C([H])C([H])=C([H])C([H])=C3[H])C(C([H])=C4[H])=[C@@]([C@@]5=C(P1(C6=C([H])C([H])=C([H])C([H])=C6[H])C7=C([H])C([H])=C([H])C([H])=C7[H])C([H])=C([H])C8=C5C([H])=C([H])C([H])=C8[H])C9=C4C([H])=C([H])C([H])=C
Application: The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.
Legal Information: Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.
Other Notes: • Technology Spotlight: Jamison Nickel (II) Precatalysts 
• A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes 
RIDADR UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., H
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp >300 °C
UNSPSC 12161600

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