VPhos Pd G3
ALDRICH/901219 - 95%
Empirical Formula (Hill Notation): C46H62NO4PPdS
Molecular Weight: 862.45
Linear Formula: C46H62NO4PPdS
Product Type: Chemical
assay | 95% |
feature | generation 3 |
form | powder or crystals |
functional group | phosphine |
Quality Level | 100 |
reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst reaction type: Cross Couplings |
Application: | Buchwald palladacycle precatalyst with new biaryl(dialkyl)phosphine ligand, VPhos, has an improved activity profile for the reductive coupling of non-aromatic heterocyclic alkyl bromides. Its combined use with a surfactant system of octanoic acid/sodium octanoate enables Negishi coupling and access to diverse C(sp3)–C(sp2) cross-coupled products. |
Other Notes: | An Improved System for the Aqueous Lipshutz–Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 95% |
UNSPSC | 12161600 |