(2R)-2-Phenyl-3,4-dihydro-2H-pyrimido[2,1-b][1,3]benzothiazole
ALDRICH/901233 - ≥95%
Synonym: (R)
CAS Number: 1316861-19-4
Empirical Formula (Hill Notation): C16H14N2S
Molecular Weight: 266.36
MDL Number: MFCD26793803
Linear Formula: C16H14N2S
Product Type: Chemical
| assay | ≥95% |
| form | powder or chunks |
| InChI | 1S/C16H14N2S/c1-2-6-12(7- |
| InChI key | ZMYZJAQMQBHNLH-CYBMUJFWSA |
| mp | 145-147 °C |
| Quality Level | 100  |
| SMILES string | C12=CC=CC=C1SC3=N[C@@H](C |
| storage temp. | 2-8°C |
| Application: | This chiral isothiourea homobenzotetramisole ((R)-HBTM) developed by the Birman lab is an organocatalyst that has been used for kinetic resolution, determination of absolute configuration, and nucleophile-catalysed, Michael–aldol-b-lactoniza) is also available. |
| Other Notes: | Technology Spotlight: Homobenzotetramisole (HBTM): A General Organocatalyst for Asymmetric Acylations [1] Determination of the Absolute Configuration β-Chiral Primary Alcohols Using the Competing Enantioselective Conversion Method  [2] Asymmetric Catalytic Synthesis of Thiochromenes via an Acyl Transfer-Initiated Cascade [3] Rapid assembly of complex cyclopentanes employing chiral, α, β-unsaturated acylammonium intermediates [4] Determination of Absolute Configuration Using Kinetic Resolution Catalysts [5] Kinetic Resolution of Secondary Alcohols Using Amidine-Based Catalysts |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥95% |
| mp | 145-147 °C |
| Storage Temp. | 2-8°C |
| UNSPSC | 12161600 |