Mes-Umemoto reagent
ALDRICH/901466 - ≥95%
Synonym: Dimesityl(trifluoromethyl)
CAS Number: 1895006-01-5
Empirical Formula (Hill Notation): C20H22F6O3S2
Molecular Weight: 488.51
Linear Formula: C20H22F6O3S2
Product Type: Chemical
| assay | ≥95% |
| form | powder |
| functional group | fluoro |
| thioether | |
| triflate | |
| Quality Level | 100  |
| reaction suitability | reagent type: catalyst reaction type: Photocatalysis |
| storage temp. | −20°C |
| Application: | Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroaren) and Ir photocatalyst (902217 or 902225 ). Product can be used with our line of photoreactors : Including Penn PhD (Z744035 ) & SynLED 2.0 (Z744080 ) |
| Other Notes: | A radical approach to the copper oxidative addition problem:Trifluoromethylat |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥95% |
| Storage Temp. | −20°C |
| UNSPSC | 12161600 |