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Rh2(S-PTAD)4

ALDRICH/905259

Synonym: Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)

CAS Number: 909389-99-7
Empirical Formula (Hill Notation): C80H80N4O16Rh2
Molecular Weight: 1559.32
Linear Formula: C80H80N4O16Rh2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-905259-250MG 250 mg
 $473.00
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 905259-250MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 905259-50MG.

 

form powder or crystals
InChI 1S/4C20H21NO4.2Rh/c4*22-17-14-3-1-2-4-15(14)18(23)21(17)16(19(24)25)20-8-11-5-12(9-20)7-13(6-11)10-20;;/h4*1-4,11-13,16H,5-10H2,(H,24,25);;/q;;;;2*+2/p-4/t4*11-,12+,13-,16-,20?;;/m1111../s1
InChI key SGEDWOHAUXKUGM-PAPHCAFZSA-J
mp >300 °C
Application: This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.
Other Notes: Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid Reactions 

Dirhodium Tetracarboxylates Derived from Adamantylglycine as Chiral Catalysts for Enantioselective C-H Aminations 

Enantioselective Synthesis of Trifluoromethyl-?Substituted Cyclopropanes 
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
mp >300 °C
UNSPSC 12161600

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