Rh2(R-PTAD)4
ALDRICH/905356
Synonym: Tetrakis[(R)
CAS Number: 909393-65-3
Empirical Formula (Hill Notation): C80H80N4O16Rh2
Molecular Weight: 1559.32
Linear Formula: C80H80N4O16Rh2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 905356-250MG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 905356-50MG.
| form | powder or crystals |
| InChI | 1S/4C20H21NO4.2Rh/c4*22-1 |
| InChI key | SGEDWOHAUXKUGM-VMLWFVNWSA |
| mp | >300 °C |
| Application: | This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereo-control. |
| Other Notes: | Dirhodium Tetracarboxylate Derived from Adamantylglycine as a Chiral Catalyst for Carbenoid Reactions   Asymmetric Synthesis of Tropanes by Rhodium-Catalyzed [4 + 3] Cycloaddition Asymmetric [4 + 3] Cycloadditions between Vinylcarbenoids and Dienes: Application to the Total Synthesis of the Natural Product (−)-5-epi-Vibsanin E |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| mp | >300 °C |
| UNSPSC | 12161600 |