Spiro[9H-fluorene-9,9′-[9H]xanthene]-2,2′,7,7′-tetramine

ALDRICH/906018

Synonym: N²,N²,N⁷,N⁷,N²′,N²′,N⁷′,N⁷′-octakis(4-methoxyphenyl)spiro[9H-fluorene-9,9′-[9H]xanthene]-2,2′,7,7′-tetramine; X60

CAS Number: 1887794-22-0
Empirical Formula (Hill Notation): C₈₁H₆₈N₄O₉
Molecular Weight: 1241.43
Linear Formula: C₈₁H₆₈N₄O₉
Product Type: Chemical

assay	>98%
color	beige
form	solid
SMILES string	COC1=CC=C(C=C1)N(C2=CC=C(OC)C=C2)C3=CC=C4C(C5(C6=CC(N(C7=CC=C(OC)C=C7)C8=CC=C(OC)C=C8)=CC=C6OC9=CC=C(N(C%10=CC=C(OC)C=C%10)C%11=CC=C(OC)C=C%11)C=C59)C%12=CC(N(C%13=CC=C(OC)C=C%13)C%14=CC=C(OC)C=C%14)=CC=C4%12)=C3

Application:	X60 can be used as a conducting polymer in the formation of perovskite based solar cells with high efficiency.
General description:	Spiro[9H-fluorene-9,9′-[9H]xanthene]-2,2′,7,7′-tetramine (X60) is a hole transporting material (HTM) with a nonplanar 3D structure which reduces the electronic coupling and charge recombination. It can be used as a starting material in the fabrication of green and cost effective p-type organic semiconductors.
General description:	X60 is cheaper alternative to Spiro-OMeTAD. X60 is a spiro[fluorene-9,9′-xanthene] (SFX) based organic hole transport material (HTM). Devices with X60 as HTM showed high power conversion efficiencies (PCEs) amounting to 7.30% in solid-state dye-sensitized solar cells (ssDSCs) and 19.84% in perovskite solar cells (PSCs). These results are competitive with the reported record PCEs of ssDSC and PSC devices based on the well-known HTM Spiro-OMeTAD. In addition, almost no hysteretic behavior could be observed in the X60-based PSCs, and the photovoltaic parameters of the devices are not affected by the scan rates used.

Purity	>98%
UNSPSC	12352116