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4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate

ALDRICH/92748 - ≥97.0%

Synonym: 2-(Trimethylsilyl)ethyl 4-nitrophenyl carbonate; TEOC-ONp

CAS Number: 80149-80-0
Empirical Formula (Hill Notation): C12H17NO5Si
Molecular Weight: 283.35
EC Number: 279-406-7
MDL Number: MFCD00042930
Linear Formula: C12H17NO5Si
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-92748-5G 5 g
$226.00
1/EA
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45-92748-25G 25 g
$661.00
1/EA
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application(s) peptide synthesis
assay ≥97.0%
form crystals
functional group carbonate
  nitro
InChI 1S/C12H17NO5Si/c1-19(2,3)9-8-17-12(14)18-11-6-4-10(5-7-11)13(15)16/h4-7H,8-9H2,1-3H3
InChI key ZAQWGGKIMQIVGM-UHFFFAOYSA-N
mp 35-40 °C
Quality Level 100 
SMILES string C[Si](C)(C)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
storage temp. 2-8°C
Application: 4-Nitrophenyl 2-(trimethylsilyl)ethyl carbonate can be used as:
• A protecting group for an amine in one of the key synthetic steps of kottamide E total synthesis.
• A starting material to prepare a cis-butene derivative, which is used as a polymer terminating agent in the synthesis of monotelechelic glycopolymers.

Other Notes: Reagent for the introduction of the TEOC-amino protecting group which can be cleaved by F-
Packaging: 5, 25 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97.0%
mp 35-40 °C
Storage Temp. 2-8°C
UNSPSC 12352108

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