Allyl bromide
ALDRICH/A29585 - ReagentPlus®, 99%, contains ≤1000 ppm propylene oxide as stabilizer
Synonym: 3-Bromo-1-propene
CAS Number: 106-95-6
Empirical Formula (Hill Notation): C3H5Br
Molecular Weight: 120.98
EC Number: 203-446-6
MDL Number: MFCD00000244
Linear Formula: CH2=CHCH2Br
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: A29585-1KG.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: A29585-500G.
| assay | 99% |
| autoignition temp. | 554 °F |
| bp | 70-71 °C (lit.) |
| contains | ≤1000 ppm propylene oxide as stabilizer |
| density | 1.398 g/mL at 25 °C (lit.) |
| expl. lim. | 7.3 % |
| form | liquid |
| InChI | 1S/C3H5Br/c1-2-3-4/h2H,1, |
| InChI key | BHELZAPQIKSEDF-UHFFFAOYSA |
| mp | −119 °C (lit.) |
| product line | ReagentPlus® |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | BrCC=C |
| storage temp. | 2-8°C |
| vapor density | 4.2 (vs air) |
| Application: | Allyl bromide can be used as a reagent to prepare: • Allyl ketones by Barbier-type allylation of various nitriles in the presence of Lewis acid. • Homoallylic alcohols by reacting with aldehydes or ketones using zinc dust as a catalyst. • 1,5-hexadiene by reductive C-C bond coupling using silver hydride cluster. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 1, 3 kg in glass bottle |
| Packaging: | 5, 100, 500 g in glass bottle |
| Symbol |      GHS02,GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H225 - H301 + H331 - H314 - H340 - H350 - H400 |
| Precautionary statements | P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| Hazard Codes | F,T,N |
| Risk Statements | 45-46-11-25-34-50 |
| Safety Statements | 53-16-26-36/37/39-45-61 |
| RIDADR | UN1099 - class 3 - PG 1 - Allyl bromide |
| WGK Germany | WGK 3 |
| Flash Point(F) | 30.2 °F |
| Flash Point(C) | -1 °C |
| Purity | 99% |
| bp | 70-71 °C (lit.) |
| mp | −119 °C (lit.) |
| Density | 1.398 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352101 |