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Allyltriphenylphosphonium bromide

ALDRICH/A36603 - 99%

Synonym: 2-Propenyltriphenylphosphonium bromide; NSC 110609; NSC 59815

CAS Number: 1560-54-9
Empirical Formula (Hill Notation): C21H20BrP
Molecular Weight: 383.26
EC Number: 216-332-6
MDL Number: MFCD00011808
Linear Formula: H2C=CHCH2P(C6H5)3Br
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-A36603-100G 100 g
 $108.00
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assay 99%
form powder
InChI 1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
InChI key FWYKRJUVEOBFGH-UHFFFAOYSA-M
mp 222-225 °C (lit.)
Quality Level 200 
reaction suitability reaction type: C-C Bond Formation
SMILES string [Br-].C=CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
Application: Reactant for:
• Preparation of a diol and carbamate chemistry library for common functional groups
• Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
• Alkene addition of frustrated Lewis pairs
• Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
• Wittig olefination of aldehydes for preparation of conjugated dienes
• Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Packaging: 100 g in poly bottle
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity 99%
mp 222-225 °C (lit.)
UNSPSC 12352002

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