Fe(dibm)3
ALDRICH/ALD00386
Synonym: Baran Olefin Cross-Coupling Catalyst; Iron tris(diisobutyrylmethane)
CAS Number: 24444-72-2
Empirical Formula (Hill Notation): C27H45FeO6
Molecular Weight: 521.49
Linear Formula: C27H45FeO6
Product Type: Chemical
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| form | solid |
| greener alternative category | Aligned  , |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/3C9H15O2.Fe/c3*1-6(2)8 |
| InChI key | LKNJSJQVZKKQHU-UHFFFAOYSA |
| mp | 96-102 °C |
| Quality Level | 100 |
| reaction suitability | core: iron |
| reagent type: catalyst | |
| SMILES string | O=C([CH-]C(C(C)C)=O)C(C)C |
| sustainability | Greener Alternative Product |
| Application: | Iron tris(diisobutyrylmethane) was reported by Baran and coworkers to be an effective catalyst in the cross-coupling of olefins. In the presence of phenylsilane (Aldrich 335150), several highly substituted and novel functionalized C-C bonds can be formed using simple and mild reaction conditions. |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here  for more information. |
| Other Notes: | The Baran Laboratory Blog: Functionalized Olefin Cross-Coupling |
| Other Notes: | Functionalized olefin cross-coupling to construct carbon–carbon bonds |
| Packaging: | 100 mg in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| mp | 96-102 °C |
| UNSPSC | 12161600 |