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2-cyanophenyl sulfofluoridate

ALDRICH/ALD00420

Empirical Formula (Hill Notation): C7H4FNO3S
Molecular Weight: 201.17
Linear Formula: C7H4FNO3S
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-ALD00420-500MG 500 mg
 $14.70
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form liquid
InChI 1S/C7H4FNO3S/c8-13(10,11)12-7-4-2-1-3-6(7)5-9/h1-4H
InChI key FWHISILUCPTNBH-UHFFFAOYSA-N
Quality Level 100 
SMILES string O=S(F)(OC1=CC=CC=C1C#N)=O
Application: The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperatre and are not air sensitive.
General description: 2-Cyanophenyl sulfofluoridate is an aryl fluorosulfate. It undergoes Suzuki-Miyaura reaction with aryl boronic acid in the presence of Pd(OAc)2 and Et3N to afford the corresponding biaryl derivative. 2-Cyanophenyl sulfofluoridate can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine.
Other Notes: Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates 
Packaging: 500 mg in glass bottle
UNSPSC 12352100

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