2-Formylphenyl sulfofluoridate
ALDRICH/ALD00422
Empirical Formula (Hill Notation): C7H5FO4S
Molecular Weight: 204.18
Linear Formula: C7H5FO4S
Product Type: Chemical
| density | 1.4545 g/mL at 25 °C |
| description | Fp: >230°F |
| form | liquid |
| InChI | 1S/C7H5FO4S/c8-13(10,11)1 |
| InChI key | SUOCJDDQQKVIKZ-UHFFFAOYSA |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | O=S(OC1=C(C=O)C=CC=C1)(F) |
| Application: | The following aryl fluorosulfate can be utilized as a cross-coupling partner in Suzuki-Miyaura reactions. The standard reaction conditions for these palladium-catalyzed C-C bond formations are ligand-free and can be performed in water, at room temperature and are not air sensitive. |
| General description: | 2-Formylphenyl sulfofluoridate is an aryl fluorosulfate. It can be synthesized from the reaction between phenol and sulfuryl fluoride in the presence of triethylamine. It undergoes Sonogashira coupling reaction with phenyl acetylene. |
| Other Notes: | Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates  |
| Packaging: | 500 mg in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| RIDADR | UN 3265 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | No data available |
| Flash Point(C) | No data available |
| Density | 1.4545 g/mL at 25 °C |
| Refractive Index | n |
| UNSPSC | 12352100 |