(1R,4R)-1-((4-(Trifluoromethyl)phenyl)sulfonyl)bicyclo[2.1.0]pentane, (-)-R-enantiomer
ALDRICH/ALD00574 - 95%
CAS Number: 2074732-95-7
Empirical Formula (Hill Notation): C12H11F3O2S
Molecular Weight: 276.27
MDL Number: MFCD30749155
Linear Formula: C12H11F3O2S
Product Type: Chemical
| assay | 95% |
| form | powder or chunks (crystals) |
| InChI key | KAKTWVYNDZQZCE-UHFFFAOYSA |
| Quality Level | 100 ![]() |
| reaction suitability | reaction type: C-C Bond Formation |
| SMILES string | FC(F)(F)c1ccc(cc1)[S](=O) |
| Application: | The following "spring-loaded" electrophile is a convenient reagent for the installation of cyclopentane to primary and secondary amines. This product is one of several synthetically useful reagents reported by Baran and coworkers for the “any-stage” installation of small, strained ring systems. |
| Other Notes: | Strain-release amination ![]() Strain-Release Heteroatom Functionalization: Development, Scope, and Stereospecificity ![]() |
| Packaging: | 100, 250 mg in glass insert |
| Symbol | GHS07 |
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P301 + P312 + P330 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 95% |
| UNSPSC | 12352200 |


