Pyridin-3-yl sulfurofluoridate
ALDRICH/ALD00586 - 95%
Empirical Formula (Hill Notation): C5H4FNO3S
Molecular Weight: 177.15
Linear Formula: C5H4FNO3S
Product Type: Chemical
| assay | 95% |
| form | liquid |
| Quality Level | 100  |
| storage temp. | 2-8°C |
| Application: | Pyridin-3-yl sulfurofluoridate can be used in the Pd-catalyzed Suzuki-Miyuara cross-coupling reaction. The fluorosulfate functionality was shown by Sharpless and coworkers to have distinct reactivity in comparison to other functional groups used in Suzuki-Miyuara reactions, such as bromides, chlorides and triflates. This inherent property provides a strong potential for selective Suzuki-Miyuara couplings for chemoselective reaction sequences. |
| Other Notes: | Palladium-Catalyzed; Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates  Chemoselective Synthesis of Polysubstituted Pyridines from Heteroaryl Fluorosulfates |
| Packaging: | 500 mg in poly bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
| RIDADR | UN 3265 8 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 95% |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352200 |