N-((1S,2S)-1-(3,5-Di-tert-butylphenyl)-2-(quinolin-2-yl)butyl)acetamide
ALDRICH/ALD00596 - ≥95%
Synonym: Chiral acetyl-protected aminoethyl quinoline ligand; Et-APAQ
Empirical Formula (Hill Notation): C29H38N2O
Molecular Weight: 430.62
MDL Number: MFCD30830353
Linear Formula: C29H38N2O
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: ALD00596-100MG.
| assay | ≥95% |
| form | powder or crystals |
| InChI | 1S/C29H38N2O/c1-9-24(26-1 |
| InChI key | NZPXTQVMJQHEBG-SHQCIBLASA |
| Quality Level | 100  |
| reaction suitability | reaction type: C-C Bond Formation |
| reagent type: catalyst | |
| reagent type: ligand reaction type: C-H Activation |
|
| SMILES string | N([C@@H]([C@H](CC)c2nc3c( |
| Application: | This chiral acetyl-protected aminoethyl quinoline (APAQ) ligand was developed by the Yu group for ligand-enabled acceleration of Pd-catalyzed enantioselective β-methylene C–H functionalization, which is important for the generation of β-chiral centers in asymmetric synthesis. |
| Other Notes: | Ligand-accelerated enantioselective methylene C(sp3)–H bond activation  |
| Packaging: | 100 mg in glass insert |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥95% |
| UNSPSC | 12352200 |