4-Bromoanisole
ALDRICH/B56501 - ≥99.0%
Synonym: 1-
CAS Number: 104-92-7
Empirical Formula (Hill Notation): C7H7BrO
Molecular Weight: 187.03
EC Number: 203-252-1
MDL Number: MFCD00000097
Linear Formula: BrC6H4OCH3
Product Type: Chemical
FT-IR Spectra for 1-Bromo-4-methoxybenzene.
| assay | ≥99.0% |
| bp | 223 °C (lit.) |
| density | 1.494 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C7H7BrO/c1-9-7-4-2-6(8 |
| InChI key | QJPJQTDYNZXKQF-UHFFFAOYSA |
| mp | 9-10 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | COc1ccc(Br)cc1 |
| Application: | 4-Bromoanisole was used in the synthesis of aryl 1,3-diketones. |
| General description: | 4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate. |
| Packaging: | 50, 100, 500 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302 - H315 |
| Precautionary statements | P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | 201.2 °F |
| Flash Point(C) | 94 °C |
| Purity | ≥99.0% |
| bp | 223 °C (lit.) |
| mp | 9-10 °C (lit.) |
| Density | 1.494 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |