2-Bromobenzaldehyde
ALDRICH/B57001 - 98%
Synonym: 2-Formylbromobenzene
CAS Number: 6630-33-7
Empirical Formula (Hill Notation): C7H5BrO
Molecular Weight: 185.02
EC Number: 229-622-2
MDL Number: MFCD00003300
Linear Formula: BrC6H4CHO
Product Type: Chemical
| assay | 98% |
| bp | 230 °C (lit.) |
| density | 1.585 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C7H5BrO/c8-7-4-2-1-3-6 |
| InChI key | NDOPHXWIAZIXPR-UHFFFAOYSA |
| mp | 16-19 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | Brc1ccccc1C=O |
| Application: | Synthetic applications of 2-bromobenzaldehyde include: • Synthesis of aza-fused polycyclic quinolines through copper-catalyzed cascade reaction. • Preparation of 1-substituted indazoles by CuI-catalyzed coupling with N-aryl hydrazides. • It is a key starting material in the total synthesis of an anticancer agent, (-)-taxol. • Palladium/copper-cataly • Fluoren-9-ones can be synthesized by annulation of arynes, generated in situ from 2-(trimethylsilyl)aryl triflates, with 2-bromobenzaldehyde in the presence of palladium(0) catalyst. • It can also be used to build a variety of steroid frameworks, in which ring A is derived from 2-bromobenzaldehyde. |
| General description: | 2-Bromobenzaldehyde is a versatile building block used in Suzuki-Miyaura and Buchwald-Hartwig reactions, cross-coupling reactions to form carbon-carbon or carbon-heteroatom bonds |
| Packaging: | 10, 25 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | 203.0 °F - closed cup |
| Flash Point(C) | 95 °C - closed cup |
| Purity | 98% |
| bp | 230 °C (lit.) |
| mp | 16-19 °C (lit.) |
| Density | 1.585 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |