Bromobenzene
ALDRICH/B57702 - ReagentPlus®, 99%
Synonym: 1-Bromobenzene; Bromobenzol; Monobromobenzene; Phenyl bromide
CAS Number: 108-86-1
Empirical Formula (Hill Notation): C6H5Br
Molecular Weight: 157.01
EC Number: 203-623-8
MDL Number: MFCD00000055
Linear Formula: C6H5Br
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: B57702-100ML.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: B57702-500ML.
| assay | 99% |
| autoignition temp. | 1051 °F |
| bp | 156 °C (lit.) |
| density | 1.474 g/mL at 25 °C |
| 1.491 g/mL at 25 °C (lit.) | |
| expl. lim. | 36.5 % |
| form | liquid |
| InChI | 1S/C6H5Br/c7-6-4-2-1-3-5- |
| InChI key | QARVLSVVCXYDNA-UHFFFAOYSA |
| mp | −31 °C (lit.) |
| product line | ReagentPlus® |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | Brc1ccccc1 |
| vapor density | 5.41 (vs air) |
| vapor pressure | 10 mmHg ( 40 °C) |
| Application: | Bromobenzene can be used as a reactant for the cross-coupling reactions such as Suzuki coupling reaction to synthesize a variety of unsymmetrical biaryls and Mizoroki−Heck reaction to synthesize various substituted alkenes. It is also an effective quencher for the fluorescence quenching of anthracene. |
| Application: | Bromobenzene was used in the synthesis of four-armed star chain transfer agent, required for the preparation of amphiphilic star graft copolymers. It was employed as organic extraction phase in the Ion pair-based dispersive liquid-liquid microextraction of ultratrace levels of gold in water samples, soils and river sediments. |
| General description: | Bromobenzene is an aryl chloride. It participates in the optimized palladium/metal oxide systems catalyzed Heck reactions of the non-activated and deactivated aryl chlorides. Heck reaction of bromobenzene with styrene using palladacycle as catalyst has been reported. It induces hepatic necrosis, via the formation of a reactive metabolite. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 100, 500 mL in glass bottle |
| Packaging: | 18 L in steel drum |
| Packaging: | 2 L in glass bottle |
| Symbol |    GHS02,GHS07,GHS09 |
| Signal word | Warning |
| Hazard statements | H226 - H315 - H411 |
| Precautionary statements | P210 - P273 - P302 + P352 |
| Hazard Codes | Xi,N |
| Risk Statements | 10-38-51/53 |
| Safety Statements | 61 |
| RIDADR | UN 2514 3 / PGIII |
| WGK Germany | WGK 2 |
| Flash Point(F) | 123.8 °F - closed cup |
| Flash Point(C) | 51.0 °C - closed cup |
| Purity | 99% |
| bp | 156 °C (lit.) |
| mp | −31 °C (lit.) |
| Density | 1.474 g/mL at 25 °C; 1.491 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |