1-Bromonaphthalene

ALDRICH/B73104 - 97%

Synonym: 1-Naphthyl bromide

CAS Number: 90-11-9
Empirical Formula (Hill Notation): C₁₀H₇Br
Molecular Weight: 207.07
EC Number: 201-965-2
MDL Number: MFCD00003868
Linear Formula: C₁₀H₇Br
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-B73104-5G	5 g	$52.70 1/EAAdd To Favorites		Add To Favorites
45-B73104-100G	100 g	$80.50 1/EAAdd To Favorites		Add To Favorites
45-B73104-500G	500 g	$155.00 1/EAAdd To Favorites		Add To Favorites

assay	97%
bp	133-134 °C/10 mmHg (lit.)
density	1.48 g/mL at 20 °C (lit.)
form	liquid
InChI	1S/C10H7Br/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChI key	DLKQHBOKULLWDQ-UHFFFAOYSA-N
mp	−2-−1 °C (lit.)
Quality Level	200
refractive index	n20/D 1.6570 (lit.)
SMILES string	Brc1cccc2ccccc12

Application:	1-Bromonaphthalene is a bromoarene that can be used in: • Palladium-catalyzed Suzuki–Miyaura coupling reaction with potassium aryltrifluoroborates without the use of phase-transfer catalysts or phosphine ligands. • The preparation of indeno annelated polycyclic aromatic hydrocarbons by reacting with o-bromobenzeneboronic acid and oligocyclic bromoarenes via Suzuki-Heck type coupling. • Ni catalyzed Kumada–Tamao–Corriu cross-coupling reaction with PhMgBr. • The preparation of arylnaphthalenes via palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with aryl boronic acid.
General description:	1-Bromonaphthalene serves as an intermediate for the synthesis of biaryl compounds via cross-coupling reactions.
Packaging:	5, 100, 500 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 - H319
Precautionary statements	P301 + P312 + P330 - P305 + P351 + P338
Hazard Codes	Xn
Risk Statements	22-36
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	230.0 °F - closed cup
Flash Point(C)	110 °C - closed cup