1-Bromonaphthalene
ALDRICH/B73104 - 97%
Synonym: 1-Naphthyl bromide
CAS Number: 90-11-9
Empirical Formula (Hill Notation): C10H7Br
Molecular Weight: 207.07
EC Number: 201-965-2
MDL Number: MFCD00003868
Linear Formula: C10H7Br
Product Type: Chemical
| assay | 97% |
| bp | 133-134 °C/10 mmHg (lit.) |
| density | 1.48 g/mL at 20 °C (lit.) |
| form | liquid |
| InChI | 1S/C10H7Br/c11-10-7-3-5-8 |
| InChI key | DLKQHBOKULLWDQ-UHFFFAOYSA |
| mp | −2-−1 °C (lit.) |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | Brc1cccc2ccccc12 |
| Application: | 1-Bromonaphthalene is a bromoarene that can be used in: • Palladium-catalyzed Suzuki–Miyaura coupling reaction with potassium aryltrifluoroborates without the use of phase-transfer catalysts or phosphine ligands. • The preparation of indeno annelated polycyclic aromatic hydrocarbons by reacting with o-bromobenzeneboronic acid and oligocyclic bromoarenes via Suzuki-Heck type coupling. • Ni catalyzed Kumada–Tamao–Corriu cross-coupling reaction with PhMgBr. • The preparation of arylnaphthalenes via palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with aryl boronic acid. |
| General description: | 1-Bromonaphthalene serves as an intermediate for the synthesis of biaryl compounds via cross-coupling reactions. |
| Packaging: | 5, 100, 500 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302 - H319 |
| Precautionary statements | P301 + P312 + P330 - P305 + P351 + P338 |
| Hazard Codes | Xn |
| Risk Statements | 22-36 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | 230.0 °F - closed cup |
| Flash Point(C) | 110 °C - closed cup |
| Purity | 97% |
| bp | 133-134 °C/10 mmHg (lit.) |
| mp | −2-−1 °C (lit.) |
| Density | 1.48 g/mL at 20 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |