1-Bromo-1-propene (cis and trans)
ALDRICH/B78203 - 98%
Synonym: 1-Propenyl bromide
CAS Number: 590-14-7
Empirical Formula (Hill Notation): C3H5Br
Molecular Weight: 120.98
EC Number: 209-671-6
MDL Number: MFCD00000186
Linear Formula: CH3CH=CHBr
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: B78203-100G.
FT-IR Spectra for 1-Propenyl bromide.
| assay | 98% |
| bp | 58-63 °C (lit.) |
| contains | copper as stabilizer |
| density | 1.413 g/mL at 25 °C (lit.) |
| form | liquid |
| InChI | 1S/C3H5Br/c1-2-3-4/h2-3H, |
| InChI key | NNQDMQVWOWCVEM-NSCUHMNNSA |
| mp | −116 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | CC=CBr |
| Application: | 1-Bromo-1-propene upon n-BuLi treatment generates the propynyllithium anion, in situ, which later undergoes nucleophilic addition reactions. Some of its other applications are: • Synthesis of organic reagents such as methyl but-2-ynoate and 1-iodopropyne. • Preparation o f intermediates in the total synthesis of (+)-aphanamol I and skyllamycins A-C. • Synthesis of allylated pyrazoles, aryl alkynyl sulfides and allenamides. |
| Packaging: | 100 g in glass bottle |
| Symbol |   GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H315 - H319 - H335 |
| Precautionary statements | P210 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | F,Xi |
| Risk Statements | 11-36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | UN 1993BE 3 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 39.2 °F - closed cup |
| Flash Point(C) | 4 °C - closed cup |
| Purity | 98% |
| bp | 58-63 °C (lit.) |
| mp | −116 °C (lit.) |
| Density | 1.413 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |