2-Bromotoluene

ALDRICH/B82006 - 99%

CAS Number: 95-46-5
Empirical Formula (Hill Notation): C₇H₇Br
Molecular Weight: 171.03
EC Number: 202-421-7
MDL Number: MFCD00000068
Linear Formula: CH₃C₆H₄Br
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-B82006-25G	25 g	$0.00 1/EA CALL FOR PRICEAdd To Favorites		Add To Favorites
45-B82006-100G	100 g	$155.00 1/EAAdd To Favorites		Add To Favorites

assay	99%
bp	58-60 °C/10 mmHg (lit.)
density	1.422 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C7H7Br/c1-6-4-2-3-5-7(6)8/h2-5H,1H3
InChI key	QSSXJPIWXQTSIX-UHFFFAOYSA-N
mp	−27 °C (lit.)
Quality Level	100
refractive index	n20/D 1.555 (lit.)
SMILES string	Cc1ccccc1Br
storage temp.	2-8°C

Application:	2-Bromotoluene was used in the synthesis of (±)-isocomene.
General description:	2-Bromotoluene is an an electron rich heteroaryl bromide. Heck reactions of 2-bromo toluene with cycloalkene (cyclododecene) and linear alkenes (dec-1-ene, allylbenzene) catalyzed by tedicyp (cis,cis,cis -1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane)-palladium complex has been studied. Vibrational spectral analysis of 2-bromobenzene by Raman and infrared spectroscopy at 50-4000cm^-1 has been investigated. Suzuki cross-coupling of 2-bromobenzene with benzeneboronic acid catalyzed by the Tedicyp-palladium complex has been studied. Suzuki coupling of 2-bromotoluene with phenylboronic acid using palladium nanoparticles supported on alumina-based oxides as catalyst has been reported.
Packaging:	25, 100 g in glass bottle

Symbol	GHS07,GHS09
Signal word	Warning
Hazard statements	H302 - H411
Precautionary statements	P264 - P270 - P273 - P301 + P312 - P391 - P501
Hazard Codes	Xn
Risk Statements	22-36/37/38
Safety Statements	36/37/39
WGK Germany	WGK 3
Flash Point(F)	174.2 °F
Flash Point(C)	79 °C