Chlorodiphenylphosphine

ALDRICH/C39601 - 96%

Synonym: P-Chlorodiphenylphosphine; ClPPh₂; PPh₂Cl; Diphenylphosphinous chloride

CAS Number: 1079-66-9
Empirical Formula (Hill Notation): C₁₂H₁₀ClP
Molecular Weight: 220.63
EC Number: 214-093-2
MDL Number: MFCD00000529
Linear Formula: (C₆H₅)₂PCl
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-C39601-25G	25 g	$69.60 1/EA	Add To Favorites
45-C39601-100G	100 g	$148.00 1/EA	Add To Favorites
45-C39601-500G	500 g	$158.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: C39601-100G.

Properties
Descriptions
Safety Info.
Basic Data

assay	96%
bp	320 °C (lit.)
density	1.194 g/mL at 25 °C
	1.229 g/mL at 25 °C (lit.)
form	liquid
functional group	phosphine
InChI	1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChI key	XGRJZXREYAXTGV-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction
	reaction type: Cross Couplings
	reaction type: Heck Reaction
	reaction type: Hiyama Coupling
	reaction type: Negishi Coupling
	reaction type: Sonogashira Coupling
	reaction type: Stille Coupling
	reaction type: Suzuki-Miyaura Coupling
refractive index	n20/D 1.636 (lit.)
SMILES string	ClP(c1ccccc1)c2ccccc2
vapor density	7.8 (vs air)

Application:	Precursors used in the synthesis of various phosphines.
Application:	Used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation.
General description:	Ph₂PCl is an efficient reagent for cross-coupling reactions and for introducing the Ph₂P group into molecules.
Packaging:	25, 100, 500 g in glass bottle

Symbol	GHS05,GHS07
Signal word	Danger
Hazard statements	H290 - H302 - H314 - H412
Precautionary statements	P273 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310
Hazard Codes	C
Risk Statements	14-34
Safety Statements	26-36/37/39-45
RIDADR	UN 3265 8 / PGII
WGK Germany	WGK 1
Flash Point(F)	280.4 °F
Flash Point(C)	138 °C
Supplemental Hazard Statements	EUH014

Purity	96%
bp	320 °C (lit.)
Density	1.194 g/mL at 25 °C; 1.229 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.636 (lit.)
UNSPSC	12352128

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