1,2-Dibromobenzene

ALDRICH/D39002 - 98%

Synonym: o-Dibromobenzene

CAS Number: 583-53-9
Empirical Formula (Hill Notation): C₆H₄Br₂
Molecular Weight: 235.90
EC Number: 209-507-3
MDL Number: MFCD00000057
Linear Formula: C₆H₄Br₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-D39002-5G	5 g	$45.10 1/EA		Add To Favorites
45-D39002-25G	25 g	$48.30 1/EA		Add To Favorites
45-D39002-100G	100 g	$136.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
bp	224 °C (lit.)
density	1.956 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C6H4Br2/c7-5-3-1-2-4-6(5)8/h1-4H
InChI key	WQONPSCCEXUXTQ-UHFFFAOYSA-N
mp	4-6 °C (lit.)
Quality Level	200
refractive index	n20/D 1.611 (lit.)
SMILES string	Brc1ccccc1Br
vapor density	8.2 (vs air)

Application:	Selective Covalent Capture of Collagen Triple Helices with Minimal Protecting Group Strategy: This study details the use of Rink Amide MBHA resin for capturing collagen triple helices, highlighting its efficiency in solid-phase synthesis (JDH Le Tracy Yu, 2020 ). Solid phase peptide synthesis: new resin and new protecting group: Introduction of a novel resin, Fmoc-Rink-Amide PEG Octagel, showcasing its application in peptide synthesis (S Ramkisson, 2018 ). Development of a novel, automated, robotic system for rapid, high-throughput, parallel, solid-phase peptide synthesis: This paper discusses the utilization of Rink Amide MBHA resin in developing an automated system for peptide synthesis (K Kiss et al., 2023 ). Synthesis of Peptoids Containing Multiple Nhtrp and Ntrp Residues: A Comparative Study of Resin, Cleavage Conditions and Submonomer Protection: The study compares different resins including Rink Amide MBHA, analyzing their efficacy in peptoid synthesis (A Lone et al., 2020 ).
Application:	It is also used as a key reactant in the synthesis of: • diborylbenzenes via palladium-catalyzed borylation of bromobenzenes • o,o′-tri- and -tetrasubstituted biphenyls via aryne cross-coupling reaction
General description:	1,2-Dibromobenzene, also known as o-Dibromobenzene, is an aromatic halogenated hydrocarbon commonly used as a precursor in various organic synthesis reactions based on the intermediate formation of benzynes.
Packaging:	5, 25, 100 g in glass bottle

Symbol	GHS07,GHS09
Signal word	Warning
Hazard statements	H315 - H319 - H335 - H411
Precautionary statements	P273 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	197.6 °F - closed cup
Flash Point(C)	92 °C - closed cup

Purity	98%
bp	224 °C (lit.)
mp	4-6 °C (lit.)
Density	1.956 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.611 (lit.)
UNSPSC	12352100

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