Hexamethyleneimine

ALDRICH/H10401 - 99%

Synonym: 1-Azacycloheptane; Azepane; HMI; Perhydroazepine; Hexahydro-1H-azepine; Homopiperidine

CAS Number: 111-49-9
Empirical Formula (Hill Notation): C₆H₁₃N
Molecular Weight: 99.17
EC Number: 203-875-9
MDL Number: MFCD00006934
Linear Formula: C₆H₁₃N
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-H10401-25ML	25 mL	$35.40 1/EAAdd To Favorites	Add To Favorites
45-H10401-100ML	100 mL	$50.80 1/EAAdd To Favorites	Add To Favorites
45-H10401-500ML	500 mL	$57.40 1/EAAdd To Favorites	Add To Favorites

assay	99%
bp	138 °C/749 mmHg (lit.)
density	0.88 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C6H13N/c1-2-4-6-7-5-3-1/h7H,1-6H2
InChI key	ZSIQJIWKELUFRJ-UHFFFAOYSA-N
Quality Level	100
refractive index	n20/D 1.466 (lit.)
SMILES string	C1CCCNCC1
vapor pressure	7.4 mmHg ( 21.1 °C)

Application:

Hexamethyleneimine (HMI) can be used in the preparation of:
• zeolitic catalysts such as MCM-22 and MCM-49
• SAPO-35, a molecular sieve
• various microporous aluminosilicates and titanosilicates
• organic-inorganic hybrid pervoskite

It can also been used in the total synthesis of various natural products and bioactive molecules such as (−)-balanol, indole estrogens, derivatives of daunorubicin and (+)-cetiedil.

Packaging:

25, 100, 500 mL in glass bottle

Symbol	GHS02,GHS05,GHS06
Signal word	Danger
Hazard statements	H225 - H300 - H314 - H331
Precautionary statements	P210 - P261 - P264 - P280 - P301 + P310 - P305 + P351 + P338
Hazard Codes	F,T
Risk Statements	11-20-25-34
Safety Statements	26-36/37/39-45
RIDADR	UN 2493 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	71.6 °F
Flash Point(C)	22 °C

Purity	99%
bp	138 °C/749 mmHg (lit.)
Density	0.88 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.466 (lit.)
UNSPSC	12352100