Lithium tri-tert-butoxyaluminum hydride
ALDRICH/L2904 - 97%
Synonym: LTBA; Lithium aluminum-tri-tert-butoxyhydride
CAS Number: 17476-04-9
Empirical Formula (Hill Notation): C12H28AlLiO3
Molecular Weight: 254.27
EC Number: 241-490-8
MDL Number: MFCD00011532
Linear Formula: LiAlH[OC(CH3)3]3
Product Type: Chemical
assay | 97% |
InChI | 1S/3C4H9O.Al.Li.H/c3*1-4( |
InChI key | BYBIDFZFKATBFH-UHFFFAOYSA |
mp | 300-319 °C (dec.) (lit.) |
reaction suitability | reagent type: reductant |
SMILES string | [H][Al]([Li])(OC(C)(C)C)( |
Application: | • Reducing agent |
Application: | Lithium tri-tert-butoxyaluminum hydride (LTBA) is a stable, mild reducing agent that is used to selectively reduce aldehydes and ketones in the presence of esters. It can also be used to reduce imidoyl chlorides to aldimines and aromatic disulfides to the corresponding thiols. |
Packaging: | 5, 25, 100 g in glass bottle |
Symbol | GHS02,GHS05 |
Signal word | Danger |
Hazard statements | H260 - H314 |
Precautionary statements | P223 - P231 + P232 - P280 - P305 + P351 + P338 - P370 + P378 - P422 |
Hazard Codes | F,C |
Risk Statements | 14/15-34 |
Safety Statements | 16-26-36/37/39-45 |
RIDADR | UN 1409 4.3 / PGI |
WGK Germany | WGK 1 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Supplemental Hazard Statements | EUH014 |
Purity | 97% |
mp | 300-319 °C (dec.) (lit.) |
UNSPSC | 12352000 |