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2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-napthalene)ruthenium(II) hexafluorophosphate

ALDRICH/L511692 - AldrichCPR

Synonym: Herzon Hydration Catalyst

Empirical Formula (Hill Notation): C25H21N2Ru · PF6
Molecular Weight: 595.48
Linear Formula: C25H21N2Ru · PF6
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-L511692-100MG 100 mg
 $29.80
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InChI 1S/2C10H8N2.C10H8.C5H5.F6P.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;1-2-6-10-8-4-3-7-9(10)5-1;1-2-4-5-3-1;1-7(2,3,4,5)6;/h2*1-8H;1-8H;1-5H;;/q;;;;-1;+1
InChI key YFGQTOCRCOVSBH-UHFFFAOYSA-N
SMILES string F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=CC=CC=N1.C3(C4=NC=CC=C4)=CC=CC=N3.[C]56[C][C][C][C][C]5C=CC=C6.[Ru+].[C]7[C][C][C][C]7
Application: Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes.

Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes 
Other Notes: Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE.
Symbol GHS05GHS07  GHS05,GHS07
Signal word Danger
Hazard statements H302 - H318
Precautionary statements P280 - P305 + P351 + P338
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
UNSPSC 12352200

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