2:1 2,2′-Bipyridine:Cyclopentadienyl(n6-napthalene)ruthenium(II) hexafluorophosphate
ALDRICH/L511692 - AldrichCPR
Synonym: Herzon Hydration Catalyst
Empirical Formula (Hill Notation): C25H21N2Ru · PF6
Molecular Weight: 595.48
Linear Formula: C25H21N2Ru · PF6
Product Type: Chemical
InChI | 1S/2C10H8N2.C10H8.C5H5.F6 |
InChI key | YFGQTOCRCOVSBH-UHFFFAOYSA |
Quality Level | 100 ![]() |
SMILES string | F[P-](F)(F)(F)(F)F.C1(C2= |
Application: | Ready mixed, single catalyst system developed by the Herzon Group for terminal alkyne functionalization. Used recently by that group to affect the anti-Markovnikov reductive hydration alkynes. Temporal separation of catalytic activities allows anti-Markovnikov reductive functionalization of terminal alkynes ![]() ![]() |
Other Notes: | Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final. NOTWITHSTANDING ANY CONTRARY PROVISION CONTAINED IN SIGMA-ALDRICH′S STANDARD TERMS AND CONDITIONS OF SALE OR AN AGREEMENT BETWEEN SIGMA-ALDRICH AND BUYER, SIGMA-ALDRICH SELLS THIS PRODUCT "AS-IS" AND MAKES NO REPRESENTATION OR WARRANTY WHATSOEVER WITH RESPECT TO THIS PRODUCT, INCLUDING ANY (A) WARRANTY OF MERCHANTABILITY; (B) WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE; OR (C) WARRANTY AGAINST INFRINGEMENT OF INTELLECTUAL PROPERTY RIGHTS OF A THIRD PARTY; WHETHER ARISING BY LAW, COURSE OF DEALING, COURSE OF PERFORMANCE, USAGE OF TRADE OR OTHERWISE. |
Symbol | ![]() ![]() |
Signal word | Danger |
Hazard statements | H302 - H318 |
Precautionary statements | P280 - P305 + P351 + P338 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
UNSPSC | 12352200 |