4-Methylmorpholine
ALDRICH/M56557 - ReagentPlus®, 99%
Synonym: N-Methylmorpholine; NMM
CAS Number: 109-02-4
Empirical Formula (Hill Notation): C5H11NO
Molecular Weight: 101.15
EC Number: 203-640-0
MDL Number: MFCD00006175
Linear Formula: C5H11NO
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: M56557-100ML.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: M56557-500ML.
| assay | 99% |
| bp | 115-116 °C/750 mmHg (lit.) |
| density | 0.92 g/mL at 25 °C (lit.) |
| dilution | (for general lab use) |
| form | liquid |
| InChI | 1S/C5H11NO/c1-6-2-4-7-5-3 |
| InChI key | SJRJJKPEHAURKC-UHFFFAOYSA |
| mp | −66 °C (lit.) |
| product line | ReagentPlus® |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | CN1CCOCC1 |
| vapor density | >1 (vs air) |
| vapor pressure | 18 mmHg ( 20 °C) |
| Application: | 4-Methylmorpholine can be used to synthesize N-butyl-N-methylmorpholinium bromide by reacting with bromobutane. |
| Application: | 4-methylmorpholine is used: • in the synthesis of N-methylmorpholine-N-oxid • as an effective and inexpensive additive for highly enantioselective arylation of aryl aldehydes catalyzed by the (S)-H8-BINOL-Ti(Oi-Pr)2 complex |
| General description: | 4-methylmorpholine, also known as N-Methylmorpholine, is a cyclic tertiary amine and is commonly used as a highly valuable solvent and a fine chemical for cellulose. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 100, 500 mL in glass bottle |
| Symbol |    GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225 - H302 - H314 |
| Precautionary statements | P210 - P280 - P301 + P312 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310 |
| Hazard Codes | F,C |
| Risk Statements | 11-22-34 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 2535 8(3) / PGII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 53.6 °F - DIN 51755 Part 1 |
| Flash Point(C) | 12 °C - DIN 51755 Part 1 |
| Purity | 99% |
| bp | 115-116 °C/750 mmHg (lit.) |
| mp | −66 °C (lit.) |
| Density | 0.92 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |