o-Phenylenediamine
ALDRICH/P23938 - flaked, 99.5%
Synonym: 1,2-Diaminobenzene; 1,2-Phenylenediamine; OPD
CAS Number: 95-54-5
Empirical Formula (Hill Notation): C6H8N2
Molecular Weight: 108.14
EC Number: 202-430-6
MDL Number: MFCD00007721
Linear Formula: C6H8N2
Product Type: Chemical
assay | 99.5% |
bp | 256-258 °C |
form | powder |
InChI | 1S/C6H8N2/c7-5-3-1-2-4-6( |
InChI key | GEYOCULIXLDCMW-UHFFFAOYSA |
mp | 100-102 °C |
Quality Level | 200 |
SMILES string | Nc1ccccc1N |
vapor density | 3.7 (vs air) |
vapor pressure | 0.01 mmHg ( 25 °C) |
Application: | o-Phenylenediamine can be used: • To prepare quinoxalines, benzimidazoles, and 1H-1,5-benzodiazepines by condensing with aryl aldehydes or ketones. • In the H2O mediated one-pot preparation of 1,2-disubstituted benzimidazoles by reacting with aldehydes in the presence of trimethylsilyl chloride. • In the copper-catalyzed synthesis of alkyne substituted quinoxalines by reacting with terminal alkynes. • In the preparation of 1,5-benzodiazepine derivatives by reacting with different ketones under neat reaction conditions via ytterbium trichloride catalyzed condensation reaction. |
Packaging: | 5, 100, 500 g in glass bottle |
Symbol | GHS06,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H301 - H312 + H332 - H317 - H319 - H341 - H351 - H410 |
Precautionary statements | P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338 |
Hazard Codes | T,N |
Risk Statements | 20/21-25-36-40-43-50/53-68 |
Safety Statements | 28-36/37-45-60-61 |
RIDADR | UN 1673 6.1 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | 276.8 °F - closed cup |
Flash Point(C) | 136 °C - closed cup |
Purity | 99.5% |
bp | 256-258 °C |
mp | 100-102 °C |
UNSPSC | 12352100 |