m-Phenylenediamine
ALDRICH/P23954 - flakes, 99%
Synonym: 1,3-Benzenediamine; 1,3-Diaminobenzene; 1,3-Phenylenediamine; MPDA
CAS Number: 108-45-2
Empirical Formula (Hill Notation): C6H8N2
Molecular Weight: 108.14
EC Number: 203-584-7
MDL Number: MFCD00007799
Linear Formula: C6H4-1,3-(NH2)2
Product Type: Chemical
assay | 99% |
autoignition temp. | 1040 °F |
bp | 282-284 °C |
form | flakes |
InChI | 1S/C6H8N2/c7-5-2-1-3-6(8) |
InChI key | WZCQRUWWHSTZEM-UHFFFAOYSA |
mp | 64-66 °C |
Quality Level | 200 |
SMILES string | Nc1cccc(N)c1 |
vapor density | 3.7 (vs air) |
vapor pressure | 0.62 mmHg ( 100 °C) |
Application: | m-Phenylenediamine may be used in the synthesis of the following: • intrinsically electrically semiconducting microparticles of semiladder poly(m-phenylenediamine-co-2-hy • extraction medium based on chitosan-poly(m-phenylenediamine) (CS-PPD) Fe3O4 nanocomposite, used as sorbent for the magnetic solid-phase extraction (MSPE) of polychlorinated biphenyls • series of terpolymers, via chemical oxidative polymerization • thin film composite (TFC) membranes based polyamide • TFC reverse osmosis (RO) membranes |
General description: | m-Phenylenediamine (MPD) is an aromatic diamine. It copolymerizes with iso- or terephthaloyl chloride and 3,5-diaminobenzoic acid or 2,4-diaminobenzene sulfonic acid (or sulfonate) to afford copolyamides by low temperature solution polymerization. MPD has been reported to be formed selectively during the hydrogenation of m-dinitrobenzene in the presence of bimetallic Ni-Pt catalysts supported on carbon. Cyclic voltammetric method has been proposed to study the electrochemical copolymerization of aniline with MPD in sulfuric acid solution. |
Other Notes: | May darken in storage |
Packaging: | 1 kg in poly bottle |
Packaging: | 15 kg in steel drum |
Packaging: | 25, 100, 500 g in poly bottle |
Packaging: | 5 g in glass bottle |
Symbol | GHS06,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H301 + H311 + H331 - H317 - H319 - H341 - H410 |
Precautionary statements | P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338 |
Hazard Codes | T,N |
Risk Statements | 23/24/25-36-43-50/53-68 |
Safety Statements | 28-36/37-45-60-61 |
RIDADR | UN 1673 6.1 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 99% |
bp | 282-284 °C |
mp | 64-66 °C |
UNSPSC | 12352100 |