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Phenylhydrazine

ALDRICH/P26252 - 97%

Synonym: Hydrazinobenzene; Monophenylhydrazine

CAS Number: 100-63-0
Empirical Formula (Hill Notation): C6H8N2
Molecular Weight: 108.14
EC Number: 202-873-5
MDL Number: MFCD00007573
Linear Formula: C6H5NHNH2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-P26252-5G 5 g
 $50.00
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45-P26252-100G 100 g
 $54.50
1/EA		 Add To Favorites
45-P26252-500G 500 g
 $108.00
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assay 97%
autoignition temp. 345 °F
bp 238-241 °C (lit.)
density 1.098 g/mL at 25 °C (lit.)
InChI 1S/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2
InChI key HKOOXMFOFWEVGF-UHFFFAOYSA-N
mp 18-21 °C (lit.)
Quality Level 200 
refractive index n20/D 1.607 (lit.)
SMILES string NNc1ccccc1
vapor density 4.3 (vs air)
vapor pressure <0.1 mmHg ( 20 °C)
Application: Phenylhydrazine can be used as a reactant in the synthesis of:
• 4, 4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol)s by reacting with aryl aldehydes and acetoacetates in presence of N-bromo sulfonamide as a catalyst via one-pot pseudo-five-component condensation.
• Thiazolidinones by treating with mercaptoacetic acid and aldehydes or ketones.
• 5-[3,3,3-trifluoro-2-(phenylhydrazono)propyl]-1-phenyl-1H-pyrazole-3-carboxylic acid by reacting with 6-(trifluoromethyl)comanic acid.

It can be also used as a precursor for the preparation of selective carboxymethylated products at N-1 and N-2 by reacting with dimethyl carbonate (DMC) in the presence of a Bronsted base and metal salts as a catalyst.
Packaging: 5 mL in glass bottle
Packaging: 5, 100, 500 g in glass bottle
Purity 97%
bp 238-241 °C (lit.)
mp 18-21 °C (lit.)
Density 1.098 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.607 (lit.)
UNSPSC 12352100

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